What may be the stable oxidation states of the transition elements with the following $d$ electron configurations in the ground state of their atoms: $3d^3$,$3d^5$,$3d^8$,and $3d^4$?

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(N/A) The stable oxidation states depend on the electronic configuration and the stability of the resulting ions.
Electronic configuration in ground state Stable oxidation states
$(i)$ $3d^3$ (e.g.,$V$) $+2, +3, +4, +5$
$(ii)$ $3d^5$ (e.g.,$Cr$ or $Mn$) For $Cr$: $+3, +6$; For $Mn$: $+2, +4, +6, +7$
$(iii)$ $3d^8$ (e.g.,$Ni$) $+2, +3$
$(iv)$ $3d^4$ There is no transition element with a $3d^4$ configuration in the ground state (as $Cr$ is $3d^5 4s^1$).

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Assertion : The free gaseous $Cr$ atom has six unpaired electrons.
Reason : Half-filled $s$ orbital has greater stability.

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